| HS Code | 559340 |
| Product Category | Water-soluble polyvinyl alcohol (PVA) vinylon fiber |
| Physical Form | Staple or chopped fiber with a white to light-yellow smooth surface |
| Water Solubility | Soluble in water; dissolution temperature typically 20–95°C depending on selected grade |
| Fiber Fineness | 1.0–4.0 dtex depending on specification |
| Staple Length | 3–150 mm adjustable; commonly 38–51 mm for textile processing |
| Tensile Strength | Approximately 5.0–9.0 cN/dtex in the dry state |
| Breaking Elongation | Approximately 5%–20% depending on grade |
| Initial Modulus | High, providing good dimensional stability |
| Density | 1.26–1.30 g/cm³ |
| Moisture Regain | Approximately 3.0%–5.0% under standard atmospheric conditions |
| Melting Behavior | No clear melting point; softens and decomposes above about 230°C |
| Alkali Resistance | Excellent in strong alkaline solutions |
| Acid Resistance | Good in common acidic solutions; limited resistance to strong oxidizing acids |
| Uv Resistance | Excellent resistance to ultraviolet light and weathering |
| Biodegradability | Biodegradable under appropriate environmental conditions |
| Safety Property | Non-toxic, formaldehyde-free, and essentially odorless |
As an accredited WanWei-Water Soluble PVA Fiber (Vinylon) factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Packaged in 25 kg moisture-proof sealed bags for safe transport and storage of WanWei-Water Soluble PVA Fiber. |
| Container Loading (20′ FCL) | Load 20′ FCL with waterproof bags, palletized, secured tightly. Ensure container dry and sealed to protect water-soluble PVA fiber from moisture. |
| Shipping | WanWei Water-Soluble PVA Fiber is packed in moisture-proof woven bags with inner plastic lining. Avoid exposure to rain, humidity, or direct sunlight during transit. The product is non-hazardous and suitable for sea, land, or rail freight. Keep cargo dry and well-ventilated to preserve fiber quality. |
| Storage | Store in a cool, dry, well-ventilated area, away from direct sunlight, heat sources, and open flames. Keep the original packaging sealed to prevent moisture absorption, as the fiber is water-soluble. Avoid high humidity and stacking under heavy load. Use within recommended shelf life to maintain quality and performance. |
| Shelf Life | Shelf life of WanWei Water-Soluble PVA Fiber is 12 months if kept in original packaging in cool, dry conditions. |
The following application scenarios for WanWei-Water Soluble PVA Fiber (Vinylon) are restricted to downstream sectors where solubility in water is the functional mechanism, not a post-cure property. Each scenario supplies the four required specification layers: governing compliance standards, formulation addition ratios, downstream production process, and terminal article types. Where published data for a specific configuration are limited, the boundary is stated explicitly rather than extrapolated.
| Downstream format | Governing compliance or test standard | Measured property | Typical water-soluble PVA fiber addition |
|---|---|---|---|
| Wet-laid nonwoven laundry bag | EN ISO 15797:2018, ISO 9073-3 | Industrial wash dissolution, dry/wet tensile | 70–100% |
| Wet-laid tea bag / filter paper | 21 CFR 176.170, ISO 1924-2 | Wet tensile energy absorption | 5–15% |
| Spunlace embroidery backing | Oeko-Tex Standard 100, ISO 9073-3 | Cross-direction wet tensile retention | 60–100% |
| Compact-spun carrier yarn | ISO 2062:2009, ISO 2060 | Breaking force after PVA dissolution | 5–15% |
| Ceramic pore former | ASTM C373-18 | Water absorption, apparent porosity, bulk density | 2–15 wt% |
| Seed tape / soluble mulch | ISO 14851-1:2019, OECD 208 | Ultimate aerobic biodegradation, seedling emergence | 100% |
Water-soluble laundry bag converting lines running continuous hydroentanglement or calendering at line speeds above 120 m/min usually record a tensile spike between 12% and 15% moisture content, which corresponds to a web temperature window of 55–65 °C during the first drying section. Selection of a dissolution temperature grade at 60 °C or 90 °C is tied to the endpoint washing cycle: low-temperature hospital laundry circuits operating at 60 °C require a grade that loses at least 90% of its dry tensile after 3 min of mechanical agitation, whereas linen service sterilization at 90 °C uses higher-dissolution grades to prevent bag collapse from steam condensation before the wash chamber door closes. Process control follows EN ISO 15797:2018 for industrial washing and ISO 9073-3 for nonwoven tensile strength. Addition ratios in the carded or wet-laid web are typically 70–100% water-soluble PVA fiber, with a residual low-melt copolyester or polypropylene binding fiber limited to 0–30% when the bag must retain neck strength during handling but still disintegrate completely in the first wash. The downstream production line includes bale opening, coarse opening through a fine carding unit with worker/stripper rollers set at 1.2–1.8 mm gap, cross-lapping to a basis weight of 25–40 g/m², hydroentanglement on a drum-type unit with water pressure between 80 bar and 250 bar, and sealing by impulse welding at 180–220 °C for 0.4–0.8 s. Terminal product types are contaminated surgical linen bags, isolation ward laundry bags, and dewatering bags for sludge or industrial filter cakes, all of which are loaded directly into washing machines or reactors and disappear without residue in the first heated cycle.
At addition rates above 8%, wet-laid tea bag and filter paper furnishes containing 3–6 mm water-soluble PVA fiber show a measurable reduction in dewatering because dissolved fiber edges migrate to the wire side and block drainage channels, leaving couch solids 1.5–3.0% lower than a pure cellulosic furnish at the same vacuum box setting. The standard operating window therefore keeps the PVA fiber addition between 5% and 15% of dry furnish weight, with 8–10% typical for tea bag paper and 5–7% for high-permeability industrial filter paper. Process control is anchored to ISO 1924-2 for tensile properties, ISO 2493 for bending resistance, and ISO 5636-3 for air permeance; food-contact grades are evaluated under 21 CFR 176.170 and EU Regulation 1935/2004. The downstream production sequence begins with pulper dispersion of refined wood pulp at 0.8–1.2% consistency, followed by PVA fiber addition after the machine chest to limit residence time below 10 min and prevent premature swelling, then delivery through a hydraulic headbox onto an inclined wire or cylinder mould at 0.5–0.8% discharge consistency. Wet pressing at 50–100 kN/m line load removes free water before multi-cylinder drying at 105–120 °C surface temperature; the PVA fiber softens and forms a hydrogen-bonded network with cellulose, but dissolution is intentionally incomplete to avoid sheet sealing. Terminal finished products include heat-sealable tea bag paper, coffee filter paper, automotive oil filter paper, and wet-strength packaging tissue; when basis weight falls below 12 g/m², the addition is capped at 5% to avoid pinhole formation. Published data for this specific configuration is limited when the furnish contains more than 20% recycled fiber, because ash and fines preferentially adsorb the dissolved PVA fraction and shift the effective retention point.
On multi-head shuttle embroidery lines with frame tensions exceeding 12 N/cm, the main failure mode in water-soluble PVA stabilizer webs is not tensile rupture but edge curling and needle drag caused by insufficient cross-machine fiber orientation, which shifts the embroidery registration by 0.3–0.8 mm on satin stitch fields. A spunlace nonwoven produced from 60–100% water-soluble PVA fiber with a basis weight of 30–50 g/m² is inserted beneath the base fabric during hooping; for high-density badge or lace motifs, two layers are stacked at 30° orientation offset to prevent stitch hole elongation. Dissolution in cold water at 20–40 °C must remove more than 99% of the backing within 5 min under gentle agitation, as verified by wet tensile retention under ISO 9073-3 and chemical residue limits under Oeko-Tex Standard 100 class I; formaldehyde content is controlled under ISO 14184-1 to below 16 mg/kg. The downstream process includes carding with random or cross-lapped batt formation, hydroentanglement at 80–150 bar on both sides, drying at 100–110 °C with non-contact impingement to avoid sheet shrinkage, and slitting to 25 cm, 50 cm, and 100 cm rolls. Finished terminal types are lace overlays, emblem backings, badge stabilizers, sequin embroidery backings, and temporary hem stabilizers for denim and terry cloth; heavier webs above 60 g/m² are restricted to designs with stitch counts below 5,000 stitches per dm² because residue removal under cold water otherwise leaves a stiff handle.
Compact spinning mills that replace conventional cotton carrier yarns with water-soluble PVA staple fiber are typically operating on frames with 120 or 240 spindles and a draft of 45–60, where the PVA fiber is introduced at 5–15% by mass during the draw frame blending step to limit short-fiber fly and to increase yarn uniformity before weaving. The PVA staple is cut to 38 mm or 51 mm and has a linear density of 1.5–2.0 dtex; its tenacity of 6–8 cN/dtex is sufficient to survive ring or compact spinning and weaving without premature fibrillation. After the greige fabric is constructed, the PVA component is removed in a pad-steam scouring range at 60–90 °C with 1–3 g/L wetting agent and 0.5–1.0 g/L soda ash, using ISO 2062:2009 breaking force and ISO 2060 linear density to verify carrier removal by mass loss and residual fiber count. The dosage directly controls the final hollow channel volume: at 10% PVA addition, a 2/30 Ne cotton yarn releases a strip of 0.15–0.25 mm void after dissolution, whereas at 15% the hollow volume becomes too large for single-jersey knitting machines above 28 gauge and may collapse during finishing. Terminal products include lightweight shirting, hollow thermal underwear, disposable industrial towels that are rinsed after use, and knitwear with reduced fiber consumption per square meter; operational boundaries require pre-drying at RH > 60% to prevent PVA filament fusion on creels, and dyes must be selected for the base fiber because the PVA is removed before dyeing at temperatures that would otherwise strip acid dyes from polyamide blends.
In alumina and cordierite green-body extrusion, the selection of PVA fiber length and titre determines whether the sintered body develops through-channel pores or isolated spherical voids; short 1–3 mm fibers at 1.0 dtex create connected capillary networks with water absorption values between 18% and 24%, while long 6 mm fibers at 2.0 dtex leave flattened channels that improve gas permeability but reduce flexural strength by 10–20%. The water-soluble PVA fiber is added at 2–15 wt% of the dry ceramic powder during high-shear mixing, with the lower bound used for dense cordierite honeycomb formulations and the upper bound for porous alumina catalyst supports; compliance testing follows ASTM C373-18 for water absorption, bulk density, and apparent porosity. The downstream process includes dry mixing with 0.5–2.0% plasticizer and 8–15% water, de-airing in a pug mill, extrusion at 20–40 bar head pressure, microwave or hot-air drying at 80–110 °C, and then either water leaching at 60–80 °C to remove the PVA fiber before sintering or direct burnout at 250–450 °C with a heating ramp of 1–2 °C/min to avoid carbon residue. The water-leach route is preferred for wall thicknesses below 1 mm because the dissolved PVA creates a temporary gel that lubricates internal channels and reduces drying cracks; however, residual sodium from the PVA manufacturing process can act as a sintering aid impurity and must be limited to <200 mg/kg for electroceramic grades. Terminal product types include porous alumina filtration membranes, catalytic converter substrate coatings, refractory thermal insulation plates, and ceramic cores for investment casting; published data for this specific configuration is limited when the pore size target falls below 0.5 µm, so validation by mercury intrusion porosimetry on the fired body is required.
For hydraulic seeding and precision vegetable tape lines, a soluble PVA web must balance soil-contact disintegration against hopper feeder robustness; the standard format is a wet-laid web of 100% water-soluble PVA fiber at 15–30 g/m², because blend ratios below 90% leave non-degradable screen residues that plug harvesting equipment in organic fields. The web is produced at 15–30 g/m², cut into strips from 10 mm to 1.2 m, and seed placement is achieved by either fluid drilling or a vacuum seed wheel followed by a second PVA web layer and moisture-activated adhesive. The compliance assessment for soil biodegradation uses ISO 14851-1:2019 aerobic degradation testing; for germination substrates, seed contact safety is checked under OECD 208 seedling emergence trials. The downstream production line typically runs a continuous wet-laid or dry-laid web former, applies a water-soluble starch or PVA adhesive at 1–3 g/m², embeds seeds at 2–5 cm spacing for vegetables or 0.5–1.0 cm for grasses, and slits the web with ultrasonic blades to seal the edges. Terminal product types include carrot and onion seed tape, grass seed mats for slope restoration, and single-dose soluble pouches for fertilizer or microplastic-free seed broadcasting. The main operational boundary is storage at RH < 50%; at higher humidity, the PVA web begins to bond to itself within 48 h, causing roll blocking and seed detachment during unrolling.
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WanWei-Water Soluble PVA Fiber (Vinylon) is a wet-spun polyvinyl alcohol staple fiber engineered for temporary structural function in nonwoven, papermaking, and textile preform processes. The polymer backbone is supplied with a controlled degree of hydrolysis and molecular weight that permits dissolution in water at pre-selected temperatures from 20 °C to 90 °C, while retaining sufficient fiber strength for carding, needle punching, hydroentanglement, and weaving. The fiber is produced in linear densities of 1.1–4.4 dtex, cut lengths of 3–12 mm, and typical breaking tenacity of 3.5–5.5 cN/dtex measured under ISO 5079:2020. It differs from high-tenacity PVA concrete fiber in that the water-soluble grade is less crystalline and dissolves completely in water rather than merely swelling. It also differs from polyethylene oxide and alginate water-soluble fibers in tensile strength, thermal stability, and compatibility with standard textile machinery. The product is supplied as staple, tow, or spun yarn, with staple form most common for dry-laid and wet-laid processes. Because dissolution is a kinetic event, the nominal temperature marked on a grade is not a complete specification; dwell time, water circulation, fabric basis weight, and water hardness must be specified for each production line.
Grade nomenclature for WanWei water-soluble PVA fiber is not harmonized across all supply chains, but the most common format encodes the nominal dissolution temperature in degrees Celsius and the staple length in millimetres. An indicative designation of 60/4 denotes a nominal dissolution temperature of 60 °C and a cut length of 4 mm; 80/6 denotes 80 °C and 6 mm. Cold-water grades are typically classed at 20–25 °C, medium-temperature grades at 40–60 °C, and hot-water grades at 70–90 °C. The temperature label should not be read as a sharp threshold. In practice, fiber swelling begins 5–10 °C below the nominal grade temperature, and complete dissolution in a compacted fabric can require a bath temperature at least 10–15 °C above the grade value. The cut length is selected for the process: 3–4 mm staple disperses more readily in wet-laid furnish, while 6–12 mm staple is preferred for dry-laid carding because longer fiber increases web cohesion during transfer. The finish level on the fiber is usually 0.10–0.30% by mass and is chosen to control static dissipation without creating a hydrophobic film that would delay water penetration.
| Parameter | Typical range | Test method or protocol |
|---|---|---|
| Fiber density | 1.26–1.30 g/cm³ | ISO 1183-1:2019 |
| Linear density | 1.1–4.4 dtex | ISO 1973:1995 |
| Cut length | 3–12 mm | Supplier lot protocol |
| Breaking tenacity | 3.5–5.5 cN/dtex | ISO 5079:2020 |
| Elongation at break | 15–25% | ISO 5079:2020 |
| Dissolution temperature | 20–90 °C | Hot-stage microscopy with forced water flow |
| Moisture regain at 65% RH | 4.0–6.0% | Supplier lot protocol |
| Finish level | 0.10–0.30% | Supplier extraction method |
Complete dissolution is controlled primarily by the degree of hydrolysis, the crystallinity from post-drawing annealing, and water temperature. PVA with a degree of hydrolysis below 88 mol% swells and dissolves more readily at ambient temperature, whereas grades above 92 mol% require hot water because stronger interchain hydrogen bonding raises the energy barrier for chain disentanglement. Differential scanning calorimetry of medium-temperature grades commonly shows a broad melting endotherm between 180 °C and 225 °C; this thermal event is not the dissolution temperature but indicates the residual crystalline domains that must be penetrated by water. The dissolution rate is not linear. A loose-stock sample of a 60 °C grade can dissolve within 10–15 min in stirred water at 70 °C, but the same fiber embedded in a hydroentangled sheet of 60 g/m² may require 20–40 min because the fabric restricts water exchange and the dissolved polymer creates a viscous boundary layer. Bath pH is usually maintained between 6.0 and 8.0. Alkaline conditions accelerate dissolution but can also saponify residual acetate groups; strong alkali is therefore not recommended for grades that must dissolve completely without residue. Borate-containing additives must be excluded because borate ions crosslink PVA and raise the effective dissolution temperature or create a gelatinous residue.
On dry-laid nonwoven lines, water-soluble PVA staple is metered with polyester, polypropylene, or viscose at 5–40 wt% as a fugitive binder. Pre-opening and carding are sensitive to stock humidity and static charge. Conditioning at 50–55% RH and 20–25 °C for 6–12 h reduces lap-ups on worker rollers and doffer transfer variability. Cylinder speed is normally kept below 120 m/min when the PVA fiber share exceeds 20 wt%; the lower crimp of water-soluble staple reduces web cohesion, and high drafting forces can open the web at the doffer. Needle punching and hydroentanglement are performed before washing because the PVA fiber must retain its geometric position until the final structure is formed. In hydroentanglement, jet pressure between 80–150 bar is used for consolidating polypropylene/PVA blends, but the water temperature must stay below the dissolution threshold of the grade. If the temperature approaches the threshold, surface dissolution begins and the fiber migrates to the fabric face, creating surface voids rather than a uniform pore network.
The most critical process window occurs in continuous wash-off lines. Bath temperature only 5–10 °C above the nominal dissolution temperature can cause swelling to precede dissolution, forming a gel layer on perforated conveyor belts and drying can surfaces. This layer cools at the edges of the line, re-precipitates, and causes web adhesion or fabric breaks. Plant-scale records reported by nonwoven producers recommend a minimum two-stage wash sequence: a first stage held at 10–15 °C above the grade temperature, and a second stage at 85–95 °C with air-scour nozzles and belt tension below 1.5 N/cm. Water jets should strike the fabric at an angle between 15° and 30° from vertical to minimize redeposition of dissolved polymer. In papermaking and wet-laid processes, the operating window is narrower. Stock temperature must remain below the grade dissolution temperature through the headbox and initial forming zone. Once the sheet is consolidated, a hot size press or wash section can remove the fiber if a porous structure is desired. For a 60 °C grade used in a papermaking furnish at 45–55 °C, the margin between good formation and premature fiber dissolution is approximately 5–10 °C. Published data for this specific configuration is limited; mill trials are required to define retention aid demand and machine speed.
In high-shear mixing for wet-laid or slurry processes, the PVA fiber is not fully inert. At mixing speeds above 1,500 rpm, fiber length can be reduced by brittle fracture; this is not necessarily a defect if the process is designed for shorter lengths, but it changes dissolution time. Dissolved PVA contributes substantially to chemical oxygen demand; the theoretical chemical oxygen demand approaches 1.8 kg O₂/kg, so effluent treatment systems must be sized for the added soluble organic load. Wastewater pH and polymer concentration should be monitored during continuous wash-off because dissolved PVA can increase liquor viscosity and reduce pump efficiency in low-shear tanks.
In three-dimensional woven preforms, water-soluble PVA yarn functions as temporary warp or weft to create channels that are later removed in a 60–90 °C bath. The spun yarn must survive weaving tensions but dissolve completely before sintering or resin infusion. A 20 tex yarn typically shows a breaking force of 2.0–5.0 N under ISO 2062:2009, which is lower than high-tenacity PVA yarn but adequate for low-speed weaving. In embroidery base fabrics, the fiber is formed into a water-soluble nonwoven at 15–35 g/m² and perforated to control stitch density. The fabric is dissolved in deionized water; calcium and magnesium ion concentrations above 50 ppm can slow dissolution and leave a mineral-polymer residue. In wet-laid papermaking, the fiber is cut to 3–6 mm and added at 1–10 wt% to the headbox. Retention aid demand increases with PVA fiber content because the fiber is non-fibrillating and rod-like; mill data indicates the stock pH should remain between 6.0 and 8.0 to prevent charge reversal on cellulose fines. This is a shallow zone for generic blending; the key restrictions are stock temperature, fiber length, and water quality.
Table 2 compares typical published values for water-soluble PVA staple with polyethylene oxide and alginate fibers used in similar fugitive-binder roles. The tensile advantage of PVA is relevant when the fiber must pass through carding or weaving without premature failure. PEO has a lower melting point and can be processed at lower temperatures, but its mechanical strength is lower. Alginate fibers dissolve readily in salt-free water but leave metal-oxide ash after incineration. Values are indicative and must be verified against the certificate of analysis for the specific lot and grade.
| Property | Water-soluble PVA | PEO | Alginate |
|---|---|---|---|
| Dissolution temperature | 20–90 °C by grade | 50–70 °C | 20–80 °C in salt-free water |
| Breaking tenacity | 3.5–5.5 cN/dtex | 1.0–2.5 cN/dtex | 1.5–2.5 cN/dtex |
| Elongation at break | 15–25% | 20–40% | 10–20% |
| Thermal stability | Degradation onset above 180 °C | Melting near 65 °C | Degradation onset above 150 °C |
| Residue after incineration | <0.5% | <0.5% | 10–20% metal-oxide ash |
| Borate sensitivity | High; crosslinks and forms gel | Low | Low |
From a regulatory and storage standpoint, water-soluble PVA fiber is supplied with certificates of conformance that reference REACH Regulation (EC) No 1907/2006 and, for electrical and electronic applications, RoHS Directive 2011/65/EU. Certain grades intended for food-contact use are assessed under FDA 21 CFR 175.300, but lot-specific migration data should be requested because surface finish and residual monomer influence compliance. Residual vinyl acetate monomer in finished fiber is typically below 5 ppm by gas chromatography, though the quantitative method is supplier-defined. The operational boundary for storage is relative humidity 70%; above this level, cold-water grades can absorb moisture and develop surface adhesion that is not reversible by drying. The fiber is incompatible with strong oxidizing agents, concentrated mineral acids, and borate-containing process additives. In aqueous blend systems, the introduction of borax or borate-based flame retardants should be avoided because even low concentrations shift the dissolution curve upward and can leave a gelatinous deposit on downstream equipment.