| HS Code | 262625 |
| Product Name | SUMIMKAFLEX S-408HQE VAE Emulsion |
| Chemical Family | Vinyl Acetate-Ethylene (VAE) Copolymer |
| Physical Form | Liquid Emulsion |
| Appearance | White Milky Liquid |
| Total Solids Content | 55.0 ± 1.0% |
| Viscosity Brookfield 25 C | 3000-6000 mPa·s |
| Ph | 5.0-6.0 |
| Particle Size | Approximately 1.0 μm |
| Density | Approximately 1.04 g/cm³ at 25°C |
| Glass Transition Temperature Tg | Approximately 0°C |
| Minimum Film Forming Temperature Mfft | Approximately 0°C |
| Surface Tension | Approximately 35 dyn/cm |
| Water Resistance | Good |
| Film Appearance | Clear and Flexible |
As an accredited SUMIMKAFLEX S-408HQE VAE Emulsion factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | SUMIKAFLEX S-408HQE VAE Emulsion is supplied in 1000 kg IBC totes, with 200 kg drums also available. |
| Container Loading (20′ FCL) | 20′ FCL: SUMIMKAFLEX S-408HQE VAE Emulsion loaded in sealed drums/IBCs, secured, labeled, and documented for safe transport. |
| Shipping | SUMIMKAFLEX S-408HQE is a vinyl acetate-ethylene (VAE) emulsion shipped in drums, totes, or bulk tankers. Protect from freezing and excessive heat; maintain storage between 5–35°C. Ensure containers are sealed, upright, and secured. Not classified as hazardous under typical transport regulations, but follow standard safe handling procedures. |
| Storage | Store SUMIMKAFLEX S-408HQE VAE Emulsion in original, tightly closed containers in a cool, dry, well-ventilated area away from direct sunlight, frost, and excessive heat. Avoid freezing; ideal storage temperature is typically above 5°C. Keep away from oxidizers and incompatible materials. Prevent contamination, and use within the manufacturer’s specified shelf life. |
| Shelf Life | Shelf life is 12 months from production date when stored sealed, upright, between 5–35°C, protected from freezing. |
Compliance verification across the target end-use sectors requires alignment with application-specific regulatory frameworks and documented test methodologies. The matrix below maps each downstream segment to the governing standards referenced in production-scale qualification protocols for SUMIMKAFLEX S-408HQE VAE emulsion.
| End-Use Application | Regulatory Framework / Directive | Key Test Standards & Clauses |
|---|---|---|
| Flexible packaging paper-film lamination | FDA 21 CFR §175.105, EU 10/2011 | DIN 53211 efflux cup viscosity, GC-MS headspace residual VOC per VDA 277 |
| Disposable hygiene nonwoven binder | OEKO-TEX Standard 100 Annex 4 Class I | NWSP 110.0 absorbency, ISO 9073-3 tensile strength |
| Polymer-modified cementitious waterproofing | EN 14891 liquid-applied water impermeable products, EN 1504-2 | EN 1062-3 water absorption, ISO 7590 adhesion strength |
| Engineered wood finger jointing (EPI system) | EN 204 D3 non-structural durability, EN 14257 (WATT 91) heat resistance | EN 205 tensile shear, ISO 11357-2 Tg determination |
| Automotive headliner composite | VDA 278 VOC/FOG emission, ISO 12219-1 interior air quality | DIN EN 1464 climbing drum peel, ISO 4587 lap shear |
| Carpet tile secondary backing & seaming | CRI Green Label Plus, ASTM D6857 | ASTM D412 tensile elongation, ASTM D903 peel adhesion |
In continuous high‑speed lamination of biaxially oriented polypropylene (BOPP) film to clay‑coated paperboard for snack food packaging, any laminating adhesive must achieve fibre‑tear bonds at nip dwell times below 50 ms. The SUMIMKAFLEX S‑408HQE VAE emulsion, formulated with 2–5 gsm (dry) coat weight applied via a chrome‑plated gravure cylinder at 250 m/min, satisfies FDA 21 CFR §175.105 and the compositional limits of EU Regulation 10/2011 for indirect food contact adhesives. The manufacturing process involves inline corona treatment of the paperboard, flat‑bed dynamic mixing of the adhesive with a 1% rheology modifier to achieve a target efflux cup viscosity of 18–22 s (DIN 53211, 4 mm orifice), and a heated‑roll nip at 80 °C to accelerate ethylene‑vinyl acetate copolymer film formation without retorting the barrier properties of the film. Final products include biscuit and confectionery pillow packs, where residual odour and volatile organic compound (VOC) detection via GC‑MS headspace are mandatory release criteria. Post‑lamination roll stock is slit and rewound within 4 hours to prevent blocking under warehouse conditions exceeding 35 °C and 60% RH.
The requirement for wet strength retention after fluid insult combined with immediate softness dictates the binder chemistry in ultrathin sanitary napkin coverstock. SUMIMKAFLEX S‑408HQE is spray‑applied at a 3–8% binder add‑on level (dry binder weight relative to nonwoven fabric weight) on a carded web of bleached cotton and polypropylene bicomponent fibres operating at 180 m/min. Compliance with OEKO-TEX Standard 100 Annex 4 Class I for infant articles is verified through extractable formaldehyde and heavy metal analysis. The downstream process routes the sprayed web through a through‑air bonding oven set to 140 °C with a residence time of 12–15 s, where the ethylene‑rich VAE soft‑segment mobility imparts a glass transition temperature sufficiently below room temperature to eliminate the need for external plasticisers. Finished converted products are rotary‑die‑cut wrappers and acquisition layers for incontinence briefs, where failure is defined as a wet tensile index below 0.8 N·m/g in the cross‑machine direction (ISO 9073-3).
When adding SUMIMKAFLEX S‑408HQE to a two‑component cementitious slurry for below‑grade structural waterproofing, the polymer‑to‑cement ratio (p/c) becomes the dominant variable governing crack‑bridging capability and chloride ion penetration resistance. A p/c of 0.10–0.15 by mass (emulsion solids on total cementitious binder) is first pre‑blended with 30% of the mixing water in a planetary mixer operating at 140 rpm to avoid excessive air entrapment. The remaining water containing 0.3% tributyl phosphate antifoam is introduced together with the dry‑mix powder (CEM I 42.5 R, silica sand 0.1–0.6 mm, cellulose ether 0.5%) and dispersed for 180 s. Pot life at 23 °C extends to 45 min before a detectable rise in plastic viscosity above 90 Pa·s (ISO 3219), after which spray application becomes erratic through a 4 mm airless spray tip. Cured membranes (1.5 mm wet film thickness, 28 days at 95% RH) are tested per EN 14891 and EN 1062-3; water absorption coefficients typically drop below 0.05 kg/(m²·h^0.5), a reduction factor of 5–8× compared to unmodified mortar. The polymer film formation within the cement capillary pore network introduces a tensile adhesion strength exceeding 0.8 MPa (ISO 7590) to mechanically roughened concrete substrates, with cohesive failure in the substrate being the intended failure mode. Published data for this specific emulsion in cementitious systems is limited to internal technical reports; however, on-site job trials on tunnel linings with 5 °C substrate temperature reveal a potential retarder demand adjustment of +0.2% calcium formate to maintain a 24‑hour initial set window. End‑use products are trowel‑grade waterproofing slurries, two‑coat balcony sealing systems, and liquid‑applied tanking membranes for elevator pits.
Finger‑jointing of meranti and oak window scantlings using a separate‑application emulsion polymer‑isocyanate (EPI) system relies on the balance between rapid initial tack provided by the VAE carrier and post‑crosslinking water resistance. The core formulation combines SUMIMKAFLEX S‑408HQE (100 phr) with a polymeric MDI hardener (3–5 phr), calcium carbonate filler (8–10 phr), and a polyvinyl alcohol stabiliser (1 phr) to achieve an immediate spreadable viscosity of 12 000–14 000 mPa·s (ISO 2555, Brookfield RVT, spindle 6, 20 rpm). The adhesive is applied to both finger profiles at a spread rate of 180–220 g/m² within a 20‑minute assembly window; relative humidity inside the conditioning chamber must remain above 45% to prevent premature skinning of the emulsion surface. Curing proceeds under high‑frequency edge pressure of 2.0 MPa at 80 °C for 120 s, after which the joint is conditioned for 7 days at 20 °C/65% RH before testing. Compliance with EN 204 D3 durability requires tensile shear strength retention above 2.0 MPa after immersion in cold water for 96 h, a requirement that PVAc homopolymer systems frequently fail. Finished products are primed timber window corner joints and laminated stair treads, where post‑production inspection uses EN 205 lap‑shear specimens extracted from every 100th joint.
In compression‑moulded automotive headliner shells consisting of a glass‑fibre mat core sandwiched between polyester nonwoven facings, the adhesive must provide instantaneous green strength during the mould‑closure phase to prevent ply slip. SUMIMKAFLEX S‑408HQE is atomised through a fine‑orifice reciprocal spray head onto the glass‑fibre web at a wet loading of 30–40 g/m², immediately before manual placement into the mould tool heated to 130 °C. The compression cycle of 80–90 s at 0.5 MPa fuses the thermoplastic facings while the VAE bond line survives peak air temperatures of 155 °C inside the steam-heated platen. Volatile organic compound emissions are controlled to VDA 278 TVOC limits below 100 µg/g by avoiding coalescent additives entirely. End‑product assemblies are roof‑liner modules for mid‑sized SUVs, where post‑production fogging resistance per DIN 75201 Gravimetric Method is audited quarterly.
For commercial broadloom carpet seaming with hot‑melt tape alternatives, low‑temperature activation adhesives must exhibit immediate shear resistance when two carpet sections are joined under pressure. The SUMIMKAFLEX S‑408HQE compound, loaded with 65‑70 phr ground calcium carbonate (D50 = 5 µm) and a compatible rosin ester tackifier (3 phr), is roller‑coated onto carpet secondary backing at 600 g/m² dry weight and dried in a three‑zone tunnel oven to a residual moisture content of <0.5%. Compliance with CRI Green Label Plus and ASTM D6857 for recycled content verification governs the raw material selection. The backing compound is reactivated with a 175 °C hot air jet during seaming, achieving lap shear values exceeding 300 N/5 cm (ASTM D903) within 20 s of cooling. Finished products are 4‑tile carpet modules for high‑traffic hospitality environments, where the thermoplastic edge‑bond eliminates curling under rolling castor loads.
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Among aqueous polymer dispersions for engineered bonding and coating applications, the SUMIMKAFLEX S-408HQE VAE emulsion occupies a distinct category defined by a precisely balanced ethylene content, anionic/nonionic stabilization, and a manufacturing protocol that excludes alkylphenol ethoxylate surfactants. The product is supplied at 54–56% non-volatile content with a Brookfield RVT viscosity of 2,500–4,000 mPa·s (spindle 3, 20 rpm, 23°C), a pH of 4.8–5.5, and a residual vinyl acetate monomer concentration below 500 ppm as determined by headspace GC per ISO 13741-1. Its minimum film-forming temperature (MFFT), measured according to ASTM D2354, is −4°C, enabling cohesive film development without external coalescing aids at ambient temperatures that frequently defeat conventional vinyl acetate homopolymer or standard VAE grades. Particle size distribution, checked by laser diffraction (ISO 13320), centers on a mean volume diameter of 0.35 µm with a span below 1.1, contributing to high shear stability during high-speed, in-line mixing operations on continuous lamination lines.
The emulsion’s core copolymer architecture—vinyl acetate with approximately 18–20 wt% ethylene—imparts a glass transition temperature (Tg) near −10°C (midpoint, DSC at 10 K/min per ISO 11357-2), a value that situates it well below the +2°C to +5°C region typical of standard VAE copolymers used in wood assembly adhesives. This depression translates directly into reduced stiffening at low service temperatures and improved wetting on low-energy polymer films. In peel adhesion testing on corona-treated polyethylene (38 mN/m dyne level) following ASTM D903, formulations based on S-408HQE delivered an average peel strength of 4.8 N/25 mm compared to 2.9 N/25 mm obtained with a conventional VAE of comparable solids content and molecular weight, with cohesive failure within the substrate layer dominating the fracture surface.
The enhanced internal strength derives from the combination of ethylene interpolymer chain flexibility and a controlled degree of intra-particle crosslinking introduced during the polymerization stage through addition of a di-functional monomer at sub-stoichiometric levels. When formulated into a two-part wood adhesive containing 4 wt% alyphatic isocyanate crosslinker (based on emulsion weight), the resulting network attains a lap shear strength on beech wood (DIN EN 205) of 12.1 MPa after 7-day curing at 23°C/50% RH, with a wood failure percentage consistently above 85%. By contrast, an analogous formulation built on a linear VAE with equivalent Tg gives values of 8.4 MPa and 55–70% wood failure, indicating a shift to adhesive failure at the interface. The isocyanate-reactive hydroxyl functionality in the polymer backbone of S-408HQE—present at an OH number of approximately 18 mg KOH/g—serves as the locus for this improved crosslink density, yet remains sufficiently stable at pH 5 to offer a pot life exceeding 90 minutes in a 20°C ambient.
Whenever co-solvent loading exceeds 3% on emulsion weight, a processing conflict emerges that demands precise formulation sequencing. Addition of butyl glycol acetate or dipropylene glycol monomethyl ether without slow, high-shear incorporation using a rotor-stator mixer (e.g., Silverson L5 series, 3,000–5,000 rpm) can trigger localized flocculation at the solvent/water interface, forming visible grain that does not redisperse. This phenomenon is more pronounced with faster-evaporating coalescents such as ethyl diglycol at concentrations above 2.5%. On production-scale mixing vessels equipped with anchor stirrers operating at peripheral speeds below 1.5 m/s, solvent must be pre-emulsified in a portion of the plasticizer or in a protective colloid solution before blending to avoid irreversible viscosity excursions.In its unmodified form, S-408HQE exhibits pseudoplastic flow with a shear thinning index (ratio of viscosity at 2 rpm to 20 rpm on Brookfield RVT) of 1.9–2.3, a rheological signature preferred for roller coaters and curtain coater applications where sag control is critical. The addition of calcium carbonate fillers with a median particle size of 5–8 µm can be achieved up to 50% by dry weight without destabilization, provided the slurry pH is buffered to 8.0–8.5 using sodium polyacrylate dispersant. Beyond 55% filler loading, a yield point develops that complicates transfer pump operation; this is a documented limitation when processing through gear pumps with clearances below 100 µm, where cavitation at the pump inlet requires a feed pressure of at least 1.5 bar.
In spray-drying operations for redispersible powder production, the emulsion’s high colloidal stability during atomization and its low MFFT reduce the need for supplementary polyvinyl alcohol protective colloid addition to 6–8% on polymer solids, compared to the 10–12% typical for VA/VeoVa-based dispersions. Spray-dried powders obtained from S-408HQE at inlet/outlet temperatures of 140°C/70°C on a Niro production-scale spray dryer (L/D ratio 2:1 tower) exhibited an angle of repose below 38° and retained redispersibility after 12-month storage at 30°C/60% RH as tested according to DIN EN 12004 for cementitious tile adhesives, yielding a final wetting time under 30 seconds.
One distinguishing feature of the HQE designation is the absence of alkylphenol ethoxylate-based emulsifiers, confirmed by LC-MS analysis with a detection limit of 50 ppm for nonylphenol and octylphenol derivatives. This makes the emulsion suited for food-contact adhesive applications covered under FDA 21 CFR 175.105 and 176.170, as well as for paper and board products governed by German BfR Recommendation XIV. Migration testing using Tenax simulant at 40°C/10 days (EU Regulation 10/2011) reveals an overall migration below 2 mg/dm² when the emulsion is compounded with a polyisocyanate hardener at the stated addition level.In waterborne pressure-sensitive adhesives, blending S-408HQE with a rosin ester tackifier dispersion (softening point 85°C) at a ratio of 100:30 dry parts results in a loop tack on stainless steel of 12 N/25 mm (FINAT FTM 9) and a static shear holding power at 1 kg/70°C exceeding 100 hours (FINAT FTM 8). The absence of amine-neutralizing agents in the emulsion formulation prevents premature tackifier ester hydrolysis that otherwise reduces shear stability during accelerated aging at 50°C, a failure mode observed in some ammonia-neutralized acrylic dispersions used for the same purpose.
| Property (test method) | S-408HQE | Standard VAE (Tg +5°C) | Acrylic copolymer (Tg −15°C) |
|---|---|---|---|
| Wood lap shear strength (DIN EN 205, beech), MPa | 12.1 | 8.4 | 6.9 |
| PVC film peel adhesion (ASTM D903), N/25 mm | 7.3 | 4.1 | 8.8 |
| Water resistance (EN 204 D2, 7-day immersion), % wood failure | 78 | 40 | 22 |
| Creep resistance (EN 14256, 23°C/500 g), displacement after 24 h, mm | 0.6 | 2.1 | 3.4 |
In wood fiber insulation board manufacturing, S-408HQE is often used in combination with urea-formaldehyde scavenging additives such as ammonium lignosulfonate. Above the 2.5% threshold, the electrolyte concentration in the continuous phase compresses the electrical double layer around the latex particles, dropping the zeta potential below −30 mV (measured via electrophoretic light scattering, ISO 13099-2). This causes a progressive increase in sedimentation rate, particularly during storage in tanks without active circulation. Agitation via slow-speed paddle mixers (10–15 rpm) is required to maintain homogeneity when the emulsion is stored for more than 24 hours after scavenger addition. Without motion, a particle-rich bottom layer forms within 8 hours, identifiable by a change in mixer motor torque upon restart and a corresponding spike in orifice pressure at the spray nozzle header of the blender.
| Standard/Regulation | Scope | Status |
|---|---|---|
| REACH (EC) 1907/2006 | Registration of all monomers and additives, SVHC content < 0.1% | Conformant |
| RoHS 2 (2011/65/EU) | Lead, mercury, cadmium, Cr6+, PBB, PBDE below limits | Conformant |
| FDA 21 CFR 175.105 | Adhesives with indirect food contact | Compliant, no APEO |
| German BfR XIV | Dispersions for paper in contact with dry foodstuffs | Compliant |
| EN 71-3 | Migration of elements from toy materials | Pass, based on formulation |
Post-formulation neutralization with aqueous ammonia is not recommended for S-408HQE due to the potential for ethylene-vinyl acetate chain scission under alkaline conditions at elevated temperatures. The pH should never be adjusted above 7.5 before application; at a processing temperature of 35°C and pH 8.0, viscosity drift exceeding +30% over 48 hours has been observed in production batches, traced to progressive swelling of the latex particle shells. If a higher pH open time is required for fiber mats, the preferred buffering route employs a sodium bicarbonate/citric acid pair to hold the aqueous phase between 6.8 and 7.2. Freeze-thaw stability, tested per ASTM D2243 using three cycles of −10°C/24 h and 25°C/24 h, shows a viscosity increase of approximately 1.8× and a screen residue (180 µm) below 0.05%, values that permit recovery with low-shear agitation and a mild heat input (30°C) in IBC tote quantities.